Bis[μ-4-methyl-2-(2-pyridylmethylsulfanyl)pyrimidine-κN 1]bis[(trifluoromethanesulfonato-κO)silver(I)]
نویسندگان
چکیده
In the centrosymmetric dinuclear title complex, [Ag(2)(CF(3)SO(3))(2)(C(11)H(11)N(3)S)(2)], the Ag(I) atom is coordinated by two N atoms from two 4-methyl-2-(2-pyridyl-methyl-sulfan-yl)pyrimidine ligands and one O atom from a trifluoro-methane-sulfonate anion in a distorted T-type coordination geometry. The ligand adopts a bidentate bridging coordination mode through one pyridyl N atom and one pyrimidine N atom. In the crystal structure, π-π inter-actions are present between adjacent pyrimidine rings, with a centroid-to-centroid distance of 3.875 (7) Å.
منابع مشابه
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010